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HHazMat SH HazMat SHIPPING PROGRAM

Introduction:

The University has instituted a campus-wide program for shipping all hazardous materials, which can include biological samples. This program is intended to be in full compliance with all applicable federal regulations. Only trained and certified personnel are permitted to package and ship the regulated materials covered by the federal manadates.

Hazardous materials can include compressed gases, flammable liquids and solids, oxidizers, poisons, corrosive materials, radioactive and biological materials and even dry ice. For shipments of biological and radioactive materials, transport or export permits and/or authorization may be required prior to shipment.

EH&S personnel will prepare the paperwork and package hazardous materials for all campus departments [see shipping instructions below]. FAQs

Regulations and Penalties:

Federal regulations have outlined specific shipping requirements for hazardous materials. The Office of Hazardous Materials Safety, which is within the United States Department of Transportation's Research and Special Programs Administration, is responsible for coordinating a national safety program for the transportation of hazardous materials by air, rail, highway and water. Depending on mode of transport and destination, these shipments are regulated by Hazardous Materials Regulations (Title 49 CFR parts 100-185) and/or International Air Transport Association (IATA). When materials are shipped out of the country, items that may not be considered hazardous in the United States may be classified as hazardous in other countries. To comply with shipping regulations, hazardous materials must be properly classified, documented, packaged, and handled.

Federal law also requires that anyone who is involved in or responsible for preparing or transporting a hazardous material must have DOT and/or IATA training and certification. No one offering hazardous materials is exempt from federal transportation requirements.

Failure to meet regulatory requirements when shipping hazardous materials may result in citations, fines and/or imprisonment. Fines to the University can range from $250 to $500,000 per violation. In addition, individual researchers and shippers may be subject to criminal penalties of up to $500,000 and five years imprisonment.

Hazardous Materials Classification and Applicability

Hazardous material regulations may apply to commercial products, chemical mixtures, and newly synthesized compounds. Various types of batteries, fuel containers and cleaning products are examples of materials that are regulated for shipment. There are nine classes of hazardous materials:  

Class or Division No.

Name of Class or Division

[for DOT definition click on Name below]

Class or Division No.

Name of Class or Division

[for DOT definition click on Name below]

1.1 to 1.6
Explosives
6.1
Poisonous Materials
2.1 to 2.3
Gases
6.2
Infectious Substances / Biological Materials
3
Flammable Liquids
7
Radioactive
4.1 to 4.3
Flammable Solids
8
Corrosives
5.1 and 5.2
Oxidizers and Organic Peroxides
9
Miscellaneous Hazardous Materials (asbestos, dry ice, PCBs)
    Forbidden Forbidden Materials
Dry Ice: Shipments with dry ice also require proper packaging and labeling. Complete and submit the On-Line Intent to Ship Hazardous Materials Form .

Hazardous material is generally defined as any substance that could adversely affect the safety of the public, handlers or carriers during transportation. Hazardous material, as defined by the DOT, is any substance that appears in the Title 49 CFR Hazardous Materials Table. (The link is found on the upper left hand side of the page Hazmat Table)

Shipping Instructions:

EH&S personnel have been trained and certified to ship hazardous materials. To ensure compliance with federal law, departments are required to ship their hazardous materials using the following procedure:

    • Important: If CAS number field on the On-Line Intent to Ship Hazardous Materials Form is left blank you will be automatically sent to an On-Line TSCA Form
  • EH&S will contact the requestor to schedule a convenient time to prepare the shipment and coordinate the required paperwork.
  • Domestic packages require 24 hours (one business day) for processing.
  • International packages require 48 hours (two business days) for processing.
  • Emergency shipments can be arranged on a case-by-case basis.
  • Special hazards and radioactive materials may take extra time to process

Frequently Asked Questions [click here]

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Class 1 - Explosives

An explosive is a substance or article (including a device) that functions by explosion, i.e. an extremely rapid release of gas and heat, or which, by chemical reaction within itself, is able to function in a similar manner even if not designed to function by explosion, unless it is otherwise classified under the provision of the regulations.

Explosives are divided into six divisions:

  1. Explosives that have a mass explosion hazard.
  2. Explosives that have a projection hazard but not a mass explosion hazard.
  3. Explosives that have a fire hazard and either a minor blast hazard or minor projection hazard or both, but not a mass explosion hazard.
  4. Explosives that present minor explosion hazard. The explosive effects are largely confined to the package and no projection or fragments of appreciable size or range are expected. An external fire must not cause virtually instantaneous explosion of almost the entire contents of the package.
  5. Very insensitive explosives that have a mass explosion hazard but are so insensitive that there is little probability of initiation or of transition from burning to detonation under normal conditions of transport.
  6. Extremely insensitive articles that do not have a mass explosive hazard and that contain only extremely insensitive detonating substances and demonstrate a negligible probability of accidental initiation or propagation.

The following list contains some examples of explosives, but is not all inclusive:


Ammonium nitrate-fuel oil mixture
Ammonium perchlorate
Ammunition
Fireworks
Black powder/gun powder
Blasting caps
Photo flash bombs
Primer cord
Flares
Fuzes
Grenades
Hexolite
Lead Azide (wetted)

Mines
Model rocket motors
Nitrocellulose
Nitroglycerin, desensitized
Picrite
Octonal
Primers
RDX
Signal devices
Toy caps
Tracers (for ammunition)
Trinitrotoluene (TNT or dynamite)



If there is a question as to whether the material you wish to ship is an explosive, notify EH&S (545-2682) and ask to have a determination made.

Return to Classifications

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Class 2 - Gases

There are three categories of regulated gases:

  1. Flammable Gas
  2. Non-Flammable/Non-Poisonous Compressed
  3. Gas Poisonous by Inhalation

Most regulated gases are listed by name in the DOT Hazardous Materials Table or in the IATA Identification Table.

The following list contains some examples of compressed gases, but is not all inclusive:

Flammable Non-Flammable/Non-Poisonous Compressed Poisonous
Aerosols Aerosols Ammonia, anhydrous
LPG (propane) Carbon dioxide Boron trichloride
Acetylene Most refrigerant gases (R124, R133, etc) Boron trifluroide
Butane CO2 fire extinguishers Hydrogen sulfide
Some refrigerant gases (R152a, R1132a, etc) Helium Carbon monoxide
Ethylene Nitrogen Compressed coal gas
Hydrocarbon gases Nitrous Oxide (also an oxidizer) Cyanogen
Hydrogen Oxygen (also an oxidizer) Chlorine
Lighters Rare gases and nitrogen mixtures Phosgene
Methane Xenon Silicon tetrafluoride

If there is a question as to whether the material you wish to ship is a compressed gas, or what division compressed gas it is, notify EH&S (545-2682) and ask to have a determination made.

Return to Classifications

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Class 3 - Flammable Liquid

Flammable liquids are defined as any liquid having a flash point of = 60.5º C (141º F). Flammable liquids may be shipped by a specific name, such as Acetone, or by a generic shipping description, such as Flammable Liquids. EH&S should be contacted to review the material to determine a proper shipping name.

The following list contains some examples of flammable/combustible liquids, but is not all inclusive:

Acetone Dimethyl formamide (DMF)
Acrylonitrile Fuel oil
Alcohols Gasoline
Aldehydes Hexanes
Amyl nitrate and nitrite Liquid hydrocarbons
Benzene Kerosene
Carbon disulfide Octanes
Some cleaning compounds Petroleum oil
Esters Some Resin solution
Methyl ethyl ketone (MEK) Rubber solution
Some amines Some silines

If there is a question as to whether the material you wish to ship is flammable/combustible, notify EH&S (545-2682) and ask to have a determination made.

Return to Classifications

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Class 4 - Flammable Solids

Class four materials are broken into three subgroups. They are:

  1. Flammable Solids
  2. Spontaneously Combustible
  3. Dangerous When Wet

Flammable Solids are defined as wetted explosives that are Class 1 explosives when dry, but are sufficiently wetted to suppress explosive properties, self-reactive materials that are thermally unstable and can undergo strong exothermic decomposition even in the absence of oxygen, and readily combustible solids that can cause fire through friction, such as matches.

Spontaneously Combustible material is defined as "Pyrophoric" materials (liquids or solids that can ignite after coming into contact with air) and as "Self-heating" materials (substances that, when in contact with air, are liable to self-heat).

Dangerous When Wet materials are materials that, when in contact with water, are liable to become spontaneously flammable or to give off flammable or toxic gas.

The following list contains some examples of Class 4 materials, but is not all inclusive:

Flammable Solids Spontaneously Combustible Dangerous When Wet
Matches Activated carbon Alkaline earth metal alloys
Nitrocellulose membrane filters Lithium alkyds Aluminum powder
Silicon powder Pentaborane Barium
Wetted explosives Phosphorus Calcium Hydride
Sulfur Oily rags Calcium carbide
Titanium Powder, wetted Seed cake Magnesium
Zinc resinate Potassium sulfide anhydrous Calcium
Naphthalene Sodium sulfide anhydrous Lithium
  Butyl lythium Sodium
    Sodium Borohydride

If there is a question as to whether the material you wish to ship is a class 4 material, notify EH&S (545-2682) and ask to have a determination made.


Return to Classifications

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Class 5 - Oxidizers / Organic Peroxides

Class five materials can be broken down into two groups:

  1. Oxidizers
  2. Organic Peroxides

Oxidizers are materials that can, generally by yielding oxygen, cause or enhance the combustion of other materials.

Organic Peroxides are any organic compounds containing oxygen in a bivalent -O-O- structure and which may be considered derivatives of hydrogen peroxide, where one or more of the hydrogen atoms have been replaced by organic radicals.

The following list contains some examples of oxidizers and organic peroxides, but is not all inclusive:

Many fertilizers Nitrites Permanganates
Chlorates Perchlorates Peroxides
Chlorites Perchlorites Chemical oxygen generators
Nitrates Persulfates Sodium superoxide


If there is a question as to whether the material you wish to ship is an oxidizer or organic peroxide, notify EH&S (545-2682) and ask to have a determination made.

Return to Classifications

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Class 6.1 - Poisonous Materials

Poisonous Materials are materials, other than a gas, known to be so toxic to humans as to pose a health hazard during transportation, or which, in the absence of adequate human toxicity data is presumed to be toxic to humans because it has been proven to be toxic or cause extreme irritation when tested on lab animals.

Poisonous materials may be shipped by a specific name, such as Phenol, or by a generic shipping description, such as Poisonous Liquids or Poisonous Solids. EH&S should be contacted to review the material to determine a proper shipping name.

Some examples of a Division 6.1 poisonous material are listed below, but this list is not all inclusive:

Some pesticides Barium compounds Phenol
Acrylamide Chloroform Cresols
Aniline Cyanides Mercury compounds
Arsenic Nicotine Xylenols
Tear Gas Vanadium compounds Sodium Azide

If there is a question as to whether the material you wish to ship is poisonous, notify EH&S and ask to have a determination made.

Return to Classifications

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Class 6 - Infectious Substances / Biological Materials

The following infectious substances and biologicals are regulated as dangerous goods.

  • Infectious Substances
  • Genetically Modified Micro-organisms and Organisms
  • Biological Products
  • Diagnostic Specimens
  • Clinical and Medical Waste
  • Select Agents and Toxins

Many other materials, which do not meet the definition of Infectious or Biological substances per IATA, may still be regulated under different IATA or DOT regulations. Because a material is not captured through one of the following definitions does not automatically exclude it from shipping regulations. Personnel shipping materials should contact EHS personnel to ensure that the material is shipped properly.

  • Infectious Substances

Infectious Substances are substances which are known to contain, or are reasonably expected to contain, micro-organisms (including bacteria, viruses, rickettsia, parasites, fungi) or recombinant micro-organisms (hybrid or mutant) that are known or are reasonably expected to cause infectious disease in humans or animals. Infectious Substances are not regulated if they are unlikely to cause human or animal disease or are incapable of spreading disease when humans or animals are exposed to them.

  • Genetically Modified Microorganisms and Organisms

These are organisms which have had genetic material purposely altered through genetic engineering in a way that does not occur naturally. There are four types of genetically modified organisms regulated as dangerous goods.

  1. Genetically modified microorganisms which meet the definition of an infectious substance.
  2. Animals which contain, or are contaminated with, genetically modified microorganisms or organisms that meet the definition of an infectious substance.
  3. Genetically modified organisms, which are known or suspected to be dangerous to humans, animals or the environment.
  4. Genetically modified microorganisms which do not meet the definition of infectious substance, but which are capable of altering animals, plants or microbiological substances in a way which is not normally the result of natural reproduction.

Genetically modified organisms and microorganisms which do not meet the definitions shown above are not regulated through this portion of IATA regulations.

  • Diagnostic Specimens

Diagnostic Specimens are defined as any human or animal material including, but not limited to, excreta, secreta, blood and its components, tissue and tissue fluids, being transported for diagnostic, or investigational purposes, but excluding live infected animals.

  • Clinical and Medical Waste

Clinical and Medical Waste is defined as wastes which are derived from the medical treatment of humans or animals or from bioresearch, where there is a relatively low probability that infectious substances are present. Infectious waste must be shipped as infectious, but waste which was infectious, but has been decontaminated may be shipped as clinical or medical waste.

  • Select Agents and Toxins

Most select agents and many toxins are regulated as dangerous goods. If these materials do not meet the definitions of other regulated materials listed above, they must be reviewed on a case by case basis to ensure that they themselves are not regulated dangerous goods. Toxins from plant, animal or bacterial sources which do not contain any infectious substances or toxins which are contained in substances which are not infectious substances must be considered for classification as a dangerous good. Please contact EHS when shipping any select agent or toxin for review prior to shipment.

If there is a question as to whether the material you wish to ship is poisonous, notify EH&S (545-2682)and ask to have a determination made.

Return to Classifications
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Class 7 - Radioactive Materials

Currently, radioactive material means any material having a specific activity greater than 0.002 microcuries per gram (µCi/g). The specific activity of a radionuclide means the activity of the radionuclide per unit mass of that nuclide. The specific activity of a material in which the radionuclide is essentially uniformly distributed is the activity per unit mass of the material.

If there is a question as to whether the material you wish to ship is a radioactive material, notify the Radiation Safety Office at EH&S 545-2682 and request a determination.

Return to Classifications
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Class 8 - Corrosive Materials

Corrosive Materials are liquids or solids that cause full thickness destruction of human skin at the site of contact within a specified period of time; or a liquid that has a severe corrosion rate on steel or aluminum. Corrosive materials may be shipped by a specific name, such as Hydrochloric Acid, or by a generic shipping description, such as Corrosive Liquid or Corrosive Solid. EH&S should be contacted to review the material to determine a proper shipping name.

Corrosive materials may be acid or alkaline, organic or inorganic. The following list contains some examples of corrosives, but is not all inclusive:

Acetic Acid Hypochlorite Solutions
Sulfuric Acid Chromic Acid
Nitric Acid Maleic Anhydride
Hydrochloric Acid Mercury
Ferric Chloride Soda Lime
Formaldehyde Sodium Hydroxide (lye)
Formaldehyde Ammonium Hydroxide
Gallium Ehtanolamine
Perchloric Acid (<50%) Potassium Hydroxide

If there is a question as to whether the material you wish to ship is corrosive, notify EH&S (545-2682)and ask to have a determination made.

Return to Classifications

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Class 9 - Miscellaneous Hazardous Materials

Miscellaneous Hazardous Materials is a catch all for materials that present a hazard during transportation but don't meet the definitions of other hazard classes. This includes material that has an anesthetic, noxious, or similar property that could cause extreme annoyance or discomfort during transportation, or any material that meets the definition of an elevated temperature material (a material which must be transported in a heated packaging), a hazardous substance (a material defined as environmentally hazardous), or a marine pollutant.

Some examples of Class 9 materials are, but are not limited to:

Asbestos Polymeric beads
Dry Ice Some Batteries
Environmentally Hazardous Substances (RQs) Many Pesticides and Fertilizers
Polychlorinated Biphenyls
 


If there is a question as to whether the material you wish to ship is Class 9 miscellaneous hazardous material, notify EH&S (545-2682) and ask to have a determination made.

Return to Classifications

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Forbidden

Some Hazardous Materials are forbidden to transport regardless of packaging, quantity or any other special arrangements. These materials are typically highly unstable, reactive, toxic or other highly hazardous items. Some of these materials may be shipped if put into solution or otherwise made stable. Those wishing to ship highly hazardous material should contact the EH&S department early in the process to prevent any delays in shipping. EH&S must be contacted early to allow enough time to develop procedures to ensure safe shipment.

Some examples of Forbidden materials are, but are not limited to:
Many multi-nitrated compounds
Many concentrated Organic Peroxides
Items which produce a strong magnetic field (aircraft only)
Chemically incompatible materials packaged together
Many explosives

Return to Classifications

 

     

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